You can check your demat account number online by following the below steps-
Through IIFL Markets Web Portal -
2. Click on the dropdown arrow at the top right corner
3. Click on Profile
4. Click on Demat Details section
From there you will be able to get your demat number.
Through Mobile App-
1. Login to Mobile App
2. Click on the three line on top left corner
3. Click on View/Manage profile
5. Scroll to Demat Details section
From there you will be able to get your demat number.